Natural gas is the soul mate of oil. Natural gas

The gas industry of the Russian Federation is one of the components of the fuel and energy complex. It includes enterprises for the production of electricity and its transportation (electric power industry), extraction and processing of all types of fuel (this is the fuel industry).

The development of the fuel industry is primarily due to the available reserves of various types of fuel. After all, if they do not exist, then there can be no prey for them. However, in reality it is more difficult.

Natural gas occupies one of the special places in the fuel, energy and raw material base due to its high consumer properties, low production and transportation costs, and a wide range of applications in many areas of human activity. Today, natural gas reserves and consumption are rapidly increasing.

Natural gas is a valuable mineral resource as the cheapest environmentally friendly fuel in preparation for the transition to a wider use of alternative non-traditional types of electricity (wind, sun, tidal, internal heat of the earth). That is why a thorough analysis of the gas industry is necessary, as one of the most important sectors for the Russian economy. It is distinguished by:

Simplification of production, does not need artificial pumping;

Ready to use without intermediate processing;

Transportation in both gaseous and liquid state;

Minimum emissions of harmful substances during combustion;

Convenience of supplying fuel in an already gaseous state during its compression (lower cost of equipment using this type of fuel);

The reserves are more extensive than other fuels (less market value);

Use in large sectors of the national economy;

A sufficient amount in the depths of Russia;

The emissions of the fuel itself during accidents are less toxic to the environment;

High combustion temperature for use in technological schemes of the national economy.

The use of natural gas leads to an increase in the efficiency of social production. Because the production of natural gas is much cheaper than the production of oil and coal. If we consider the cost of coal (in terms of 1 ton of standard fuel) for 100%, then the cost of gas will be equal to only 10%.

Also, natural gas is one of the most highly efficient sources of fuel and energy resources. Natural gas has a high natural productivity of labor, which contributes to its widespread use in many sectors of the national economy. Favorable natural preconditions for natural gas and a high level of scientific and technological progress in its transportation largely ensure the accelerated development of the gas production industry.

The gas industry of the Russian Federation is still a very young branch of the fuel complex. It includes the following elements:

Extraction of natural gas;

Production of associated gas;

Combustible gas production from coal and shale;

Gas storage.

The main proven sources are concentrated in two regions - in the CIS countries and the Middle East, despite the large distribution of proven gas reserves on the globe.

compressed natural gas motor fuel

Of the total volume of explored reserves, Western Siberia accounts for 36.2 trillion cubic meters. m (77.7%), on the shelf of the northern seas - 3.2 trillion cubic meters. m (6.8%), to Eastern Siberia and the Far East - 2.8 trillion cubic meters. m (6%) (see Fig.1.1). In general, the explored gas reserves in Russia (free gas and gas caps) amount to approximately 48 trillion cubic meters. m.

Rice. 1.1

As can be seen from Figure 1.1, almost 73% of gas reserves are located in 22 unique (over 500 billion cubic meters of gas) fields, such as Orenburgskoye, Urengoyskoye, Yamburgskoye, Zapolyarnoye, etc. 104 large fields contain about 24% of gas reserves, and only 3% of explored reserves account for numerous (663) small and medium-sized deposits Federal State Statistics Service [Electronic resource] - Access mode: http: // irkutskstat. gks.ru/ (date of access: 02.05.2016). ...

It should be noted that the gas industry is a source of significant income for the state, therefore, a fairly large amount of money and attention from the government is spent on its development. This leads to the fact that the industry is constantly developing and improving. This is due to the fact that new pipelines are being introduced, which are of high quality and reliable. Unique technologies for gas production, machinery and modern equipment are used. All this leads to the fact that the gas industry is constantly developing and becomes a source of such a large income that for these funds it is possible to develop another industry. New gas fields are being discovered, which increases profits. We can say with confidence that the gas industry expects effective and constant development, which will affect the country's economy as a whole. It should also be noted that Gazprom acts as a monopoly, so there is no need to worry that the gas sector will be unstable, since a single monopoly structure will prevent the collapse of economic ties, as it might in a competitive environment. At the same time, the company constantly introduces new innovative technologies, participates in various projects, as well as all its activities are aimed at increasing the efficiency of the gas industry.

Today the demand for gas in Russia is growing. Gas is consumed by over 2 thousand cities, 3.5 thousand urban-type settlements, more than 190 thousand rural settlements. The share of gas in the fuel balance of Russia is 48.8%. Over the past decade, the volume of gas supplies in the domestic market has increased significantly. It is safe to say about a significant growth potential, since at the moment gasification in rural areas reaches only 31%.

Gas is used in metallurgical, cement, light, food industries of the national economy as a fuel. Gas is also used as a feedstock for the chemical industry. Gas often replaces conventional fuels such as coal, fuel oil or peat. Due to the high quality of the gas, the production efficiency increases during its application. For example, in the metallurgical industry, the use of gas allows you to save expensive coke, increase the productivity of furnaces and improve the quality of the metal produced. The use of gas at thermal power plants can significantly save on fuel transportation, increase the operating time of boilers, automate power plant control and reduce the number of required personnel. Recently, an important area of ​​application of gas has been its use as a fuel for cars. This approach allows you to reduce the emission of harmful substances generated during the operation of a car engine by 40-60%.

In Russia, 93% of pig iron, 59% of open-hearth steel, 49% of rolled ferrous metals, 100% of refractories, 89% of sheet glass and 45% of precast concrete are produced using natural gas. The share of natural gas in the consumption of fuel and energy resources by power plants reaches 61% Federal State Statistics Service [Electronic resource] - Access mode: http: // irkutskstat. gks.ru/ (date of access: 02.05.2016). ...

The engineering industry is also one of the largest consumers of natural gas. Combustible gas accounts for about 40% of the fuel balance of the machine-building industry. Heating and heat treatment furnaces are the main consumers. The use of natural gas in these furnaces instead of other types of fuel makes it possible to reduce the cost of heating, improve its quality, increase the efficiency of the furnaces and create more favorable sanitary and hygienic conditions in production facilities. Enterprises in this industry have a diverse structure of energy consumption.

The availability of technological equipment at enterprises with different temperature conditions opens up the possibility of widespread use of the method of integrated use of natural gas. Autonomous combined schemes for the use of natural gas for the simultaneous generation of heat and electricity are of great interest in industrial power engineering. In such installations, natural gas is burned in a gas turbine or internal combustion engine that drives electric generators.

The method of direct reduction of iron from ores is also based on the use of gas fuel. The use of gas in cupolas reduces coke consumption by half.

In the food industry, gas is used for drying vegetables, fruits, food products, bakery and confectionery products. The following gases are widespread as heat carriers: air and, less often, gaseous products of exothermic processes (ammonia oxidation, sulfuric anhydride production, etc.), combustion products.

The use of natural gas opens up wide opportunities for the creation of simple, less metal-intensive and more economical boilers (steam and hot water) operating on natural gas. The efficiency of boiler installations at power plants when switching from solid to gas fuel increases by 1-4%; the number of service personnel is reduced by 21-26%. The total reduction in fuel consumption due to an increase in the efficiency and a decrease in electricity consumption for auxiliary needs is 6-7%. Combustion of natural gas in the furnaces of low-capacity boilers increases the efficiency by 7-20% in comparison with boilers using solid fuels (depending on the type of fuel) and allows an increase in productivity by 30% or more.

Natural gas is also widely used in public utilities. And it is impossible to imagine the existence of our world without this useful substance. Life would just stop. The use of natural gas in the everyday life of a modern person is so familiar and commonplace that it seemed that it has always been so. It is very convenient to use gas equipment, and, most importantly, it is economically profitable. In fact, gas stoves, gas water heaters, gas water heaters do the same job as their electrical counterparts, but they ask for much less wages for their work. Especially if you act wisely, and in addition to gas equipment, you have gas meters at home.

The use of liquefied gas for heating greenhouses in the cold season makes it possible to automate the heating process, as well as to increase the level of carbon dioxide production for the successful photosynthesis of greenhouse plants. Additional heat is required even for small barns or stables, and liquefied gas is effectively used for drying or disposing of feathers.

Liquefied gas is indispensable in many areas of farming and is used not only for heating industrial and residential premises. Due to the high calorific value of propane, it is possible to grow, handle and store crops with maximum efficiency, while observing the required level of environmental safety.

Using liquefied gas as energy for a grain dryer, it is required to install an autonomous gas supply system. Depending on the production capacity, containers of various sizes are installed. An underground gas pipeline runs from the gas storage facility to equipment using gas. The amount of gas in the tank can be monitored using telemetry devices, this will allow timely deliveries of fuel.

During the cold season, a variety of heating systems are used to generate heat in greenhouses and greenhouses, with the primary economic benefit being the energy source.

The use of energy efficient equipment such as infrared heaters will reduce the cost of LPG. Radiant heating is characterized by limited heat loss, efficient use of resources and minimal emissions. For facilities remote from the mains, the use of liquefied gas is the optimal solution.

Farms are usually located at a considerable distance from the main energy lines. At the same time, energy is one of the most important factors in the operation of the farm: energy supply is required for space heating and water heating, organic waste incineration, steam production and other technological processes. These tasks are effectively solved by installing an autonomous gas supply system. Liquefied gas is the optimal source of energy if the farm is located away from natural gas networks. Liquefied gas is delivered throughout Russia, even to the most remote regions. The superior calorific value and efficiency of propane will keep your income in the harshest winter.

In medical practice, the use of various gases is widespread. The most common are oxygen and nitrogen.

The scope of application of medical oxygen is quite large - this is the enrichment of gas mixtures used for breathing disorders, decompression sickness, for the treatment of asthmatic disease of various etiologies, for the prevention of hypoxia - in the manufacture of oxygen cocktails and filling oxygen cushions. The most popular now are oxygen concentrators, due to their safety, reliability, mobility, economic profitability and, of course, the high concentration of "produced" oxygen - up to 95%. The main sources of oxygen are primarily oxygen concentrators, special devices for the chemical production of oxygen, and then oxygen enrichment systems and cylinders with liquid or gaseous oxygen. Medical oxygen differs from any other in its higher concentration and the absence of various impurities.

It is necessary to use medical oxygen in emergency situations, during major surgical operations, during anesthesia, where artificial ventilation is required, during resuscitation measures. Such serious diseases as stroke, heart attack, chronic respiratory failure also require oxygen treatment. But in Russia, medical oxygen is one of the most expensive medicines - oxygen is brought to many hospitals in our country from other cities.

Another gas used in medicine, but in smaller volumes, is helium. Pure helium gas is used for the production of breathing mixtures. Air filled with helium is several times lighter than ordinary air and, accordingly, it is several times easier to breathe. The most common mixtures of helium and oxygen in medicine are due to their optimal viscosity. This "helium" air is used to treat asthma, suffocation and other diseases associated with breathing difficulties.

Like oxygen, nitrogen finds its use in liquid and gaseous form. In medical practice, the spread of its use is about 90%. It is used to preserve blood, blood-containing preparations, blood substitutes, to keep various organs and tissues frozen, as well as to prepare some powder medicines. Do not forget about another area where medical nitrogen is used - inhalation anesthesia. Nitrous oxide is used in surgical gynecology, painful childbirth, during surgical operations and sometimes even with myocardial infarction, since its toxic effect on the respiratory and cardiovascular systems is extremely insignificant. Nitrous oxide is also used to relieve pain in acute pancreatitis attacks, to relieve pain in acute coronary insufficiency. The supply of medical nitrogen is carried out in special steel cylinders with a volume of 10 liters, filled at the enterprises.

Today natural gas is the most economical, environmentally friendly and safe fuel. The cost of 1 cubic meter m of gas as of May 1, 2016 for transport on average in Russia is 14 rubles. Natural gas belongs to the safest class of combustible substances. Moreover, the engine of such a vehicle meets the highest standards - Euro-5 and Euro-6. Two types of natural gas are used as a motor fuel: compressed gas (CNG) and liquefied gas (LNG).

Target market segments: compressed natural gas - passenger, light freight, light vehicles and utility vehicles; liquefied natural gas - main road, rail, water transport, quarry and agricultural machinery.

So, the products of the industry under consideration provide industry (about 45% of the total national economic consumption), thermal power industry (35%), and public utilities (more than 10%). Gas is the most environmentally friendly fuel and a valuable raw material for the production of chemical products. More than 30 different gases are used in technology. Gases in technology are mainly used as fuel; raw materials for the chemical industry: chemical agents in welding, gas chemical thermal treatment of metals, creating an inert or special atmosphere, in some biochemical processes, etc.; heat carriers; a working medium for performing mechanical work (firearms, jet engines and projectiles, gas turbines, steam and gas installations, pneumatic transport, etc.): a physical medium for a gas discharge (in gas discharge tubes and other devices).

Lighting a burner in the kitchen, few housewives think about how long ago people began to use natural gas as fuel. This history goes back not centuries, but millennia: in the IV century BC. e. the Chinese heated and illuminated their homes with a smokeless, bluish fire.

In Russia, the industrial development of natural gas fields began in the last century, and before that it was found only in the extraction of oil or drilling wells for water.

Russian ingenuity has always helped people make good use of everything that comes along the way. When in the Saratov province a merchant began to drill an artesian well and discovered not water, but fire, he took advantage of the situation and organized glass and brick production there.

Other industrialists adopted his experience, and useless underground gas began to gradually turn into valuable fuel.

What is natural gas

One of the most important minerals is natural gas, which is used both as fuel and for the needs of the chemical industry. This colorless and odorless substance can be very dangerous.

Without special devices, it is impossible to determine that a flammable component is present in the air, which may cause a fire.

From the point of view of ecology, gas is the cleanest natural fuel, because during combustion it emits much less harmful compounds than wood, coal or oil.
This quality makes it in demand in all countries of the world. States that have large deposits on their territory use it both for their own needs and for sale to other peoples. Nature gave Russia the richest Urengoy, Kazakhstan - the Karachaganak field, and she did not deprive the countries of the Persian Gulf, the USA, Canada.

The bowels of the earth have created not only huge underground reservoirs of natural gas - its reserves are also stored in a more compact form. In cold regions and under the ocean floor, where the hydrostatic pressure reaches 250 atmospheres, gas combines with formation water and a solid substance is formed - gas hydrate. In small volumes, there is a huge amount of natural fuel; in bound form, the gas decreases up to 220 times.

Origin of natural gas

Hundreds of millions of years ago, an ocean splashed on the site of today's continents. The dead inhabitants of the water element fell to the bottom and turned into silt. They could not decompose because there was no air to oxidize or bacteria to cause decay. The movement of the earth's crust contributed to the immersion of these masses deeper and deeper. High pressure and temperature caused chemical reactions in which the carbon of organic residues combined with hydrogen, and new substances were formed - hydrocarbons.

If the pressure and temperature were not very high, high molecular weight fluids were obtained, which eventually turned into oil. When these parameters reached large values, low molecular weight gases were formed.

The joints were covered with sedimentary rocks and found themselves deep below the surface of the earth. Geologists find these minerals at a depth of one to six kilometers.

There is another theory of the formation of natural gases. Some scientists believe that as a result of tectonic movements, hydrocarbons gradually rise upward, where the pressure is not so great, and form large accumulations of oil and

Terrestrial rocks are not monolithic - they have small cracks and pores. Gaseous substances fill these voids, so natural gas is present not only in, but also in rocks located at great depths.

Natural gas properties

Natural gas is not a separate substance - it is a mixture of different components, the main of which is methane.

It is impossible to find two absolutely identical samples from different deposits: in each of them the composition is individual.

For its formation, various organic residues were used; the conditions for the occurrence of chemical reactions were also not the same.

No scientist can give you the chemical formula of natural gas - he can only tell you the percentage of its constituent substances. In addition to methane, additional components are hydrocarbons:

  • ethane;
  • propane;
  • butane;
  • hydrogen;
  • hydrogen sulfide;
  • carbon dioxide;
  • nitrogen;
  • helium.

The physical properties of fossil fuels also follow from the chemical composition. There are no exact parameters either, because they depend on the percentage of the components:

  • density - 0.68–0.85 kg / m3 in gaseous form and 400 kg / m3 in liquid form;
  • spontaneous combustion - at a temperature of 650 ° C;
  • specific heat of combustion - 28–46 MJ / m³.

Since natural gas is almost twice lighter than air, it rises upward. A person cannot suffocate when he finds himself at the bottom of the lowland. But there is another danger: if 5 to 15% of the volume of natural gas is present in the air, the mixture becomes explosive.

On its basis, a gas-fuel system used in cars has been developed. The octane rating of natural gas used in engines ranges from 120 to 130.

Combustion of natural gas is a complex process in which chemical energy is converted into heat. Burning is complete and incomplete.

The need for cleaning

At first glance, there is nothing difficult in using gas. Lay pipes, drill a well - and blue fuel, which is in the depths under high pressure, will flow to the boilers and stoves by itself. But not everything is so simple - natural gas contains impurities that can harm pipelines, appliances or human health.

There is a lot of moisture in the depths of the earth, which can enter into chemical reactions or create condensation, and a large amount of it interferes with the passage of gas. Hydrogen sulfide causes metal to rust and equipment quickly deteriorates. To remove harmful components from raw materials, special cleaning stations are installed at the fields.

Delivery

Gas pipelines are many thousands of kilometers long; the initial flow energy is not enough to cover such distances.

No matter how smooth the inner surfaces are, frictional force still arises, the gas loses speed and heats up.

There are other ways of transporting gas, but so far pipelines are the most economical.

Gas smell

Natural gas is odorless, so why do apartment residents immediately feel if there is a leak somewhere? For our safety, special odorants are added to the blue fuel, the slightest presence of which is sensitive to a person's sense of smell. Usually, this role is played by mercaptans, which have such an unpleasant odor that it is impossible not to notice it.

Throughout its history, humanity has been warmed by burning various types of fuel.

If you think so, then life is generally dangerous)
I hope that alternative energy sources will soon become popular .. Earth's reserves are not eternal - this should be remembered too, everything has its beginning and end.
But about the greenhouse effect in general, the thing is interesting - after all, some deny that this is the influence of anthropogenic factors, like the activities of industries and stations. Personally, I do not agree with them, yet humanity makes its contribution to the destruction of the planet every minute ..

Naturally, natural gas has less impact on the planet when it burns than all the same firewood or coal, but you shouldn't deny its harm and immediate danger either. First of all, gas is a volatile substance and its unsuccessful storage or distribution can lead to terrible, disastrous consequences for both humans and the surrounding world. All hope is for scientists that they will soon find a solution to protect the Earth from slow death, preventing the greenhouse effect ...

Instructions

Natural gas can be used to fill gas lamps intended for lighting. Methane itself is used as a feedstock for the production of acetylene, ammonia, methanol and hydrogen cyanide.

At the same time, natural gas is a raw material base in the production of ammonia. Almost three quarters of all ammonia is used for the production of nitrogen fertilizers.

Hydrogen cyanide, already obtained from ammonia, together with acetylene serves as the initial raw material for the production of various synthetic fibers. Acetylene can be used to produce various layers-kats, which are quite widespread in industry and in everyday life. Acetate silk is also produced with it.

In the chemical industry, methane is used not only for the production of various plastics, but also for the production of organic acids and alcohol. It was with the use of natural gas that it became possible to create many chemicals that are not in nature, for example, polyethylene.

Natural gas is one of the best fuels used for industrial and domestic needs. Its value as a fuel also lies in the fact that this mineral fuel is quite environmentally friendly. When it burns, much less harmful substances appear if with other types of fuel. That is why natural gas is one of the main sources of energy in all human activity.

Hydrogen it is rarely found in its pure form on Earth, but it is very common in the composition of compounds: it is found in water, in plant and animal organisms, in natural gases. In space, however, it is the most common element.

You will need

  • Publication on general chemistry or a textbook on chemistry, grade 8-9.

Instructions

In order to define hydrogen, you need to know some of it. Some of them will help to cope with the task in a short time, while others require being in a chemical one. You don't have to use all the methods, one or two are enough.
Hydrogen- the lightest of all. For example, there may be a problem - to determine hydrogen, having in the presence of several vessels with unknown gases. In this case, you need to pay attention to the vessel - the hydrogen must be either inverted or closed (possibly with glass, which can be moved aside for further determination). Otherwise, the hydrogen will evaporate. This gas has no smell and color.

When ignited, hydrogen burns with a non-luminous flame, and water is formed. A good way of identifying, but very dangerous because a mixture of hydrogen and oxygen is called explosive gas because of its explosive properties. Although it should be noted that at low temperatures this will not work. Only at 300 ° C does a small amount of water begin to form, at 500 ° C a fire occurs, and at 700 ° C an explosion occurs.

If the gas is passed over a heated copper oxide, the copper will recover - the result is a reddish metal. To carry out this experiment, it is necessary to observe safety rules and, preferably, is in the appropriate (in the laboratory).

Currently, natural gas is widely used in the fuel, energy and chemical industries.

Natural gas is widely used as a cheap fuel in residential and apartment buildings for heating, water heating and cooking. It is used as fuel for cars, boilers, thermal power plants. It is one of the best types of fuel for domestic and industrial needs. The value of natural gas as a fuel also lies in the fact that it is an environmentally friendly mineral fuel. When it burns, much less harmful substances are formed compared to other types of fuel. Therefore, natural gas is one of the main sources of energy in human activity.

In the chemical industry, natural gas is used as a raw material for the production of various organic substances, for example, plastics, rubber, alcohol, organic acids. It was the use of natural gas that helped synthesize many chemicals that do not exist in nature, such as polyethylene.

At first, people had no idea about the beneficial properties of gas. In oil production, it is often associated gas. Previously, such associated gas was simply burned right at the production site. In those days, it was unprofitable to transport and sell natural gas, but over time, efficient methods of transporting natural gas to the consumer were developed, the main of which is pipeline. With this method, gas from the wells, previously purified, enters the pipes under enormous pressure - 75 atmospheres. In addition, a method of transporting liquefied gas is used in special tankers - gas carriers. Liquefied gas is safer to transport and store than compressed gas.

And the burning of natural gas in a number of states is prohibited by law, but in some countries it is still practiced today ...

Did you know that ...

Pure natural gas is colorless and odorless. In order to be able to detect a gas leakage by smell, a small amount of substances with a strong unpleasant odor are added to it. Ethyl mercaptan is most often used for this purpose.

DEFINITION

Natural gas Is a mixture of gases (organic and inorganic) formed in the bowels of the Earth during the anaerobic decomposition of organic substances. Mineral resource.

A significant component of natural gas is methane (70 - 98%), followed by ethane, propane and butane; among gases of inorganic nature, natural gas can include carbon monoxide and carbon dioxide, nitrogen, inert gases, hydrogen, hydrogen sulfide. The chemical composition of natural gas (volumetric content of each gas) can vary from field to field.

Chemical properties of natural gas

Since natural gas is a mixture of gases, it is impossible to indicate what chemical properties are characteristic for it, since each substance included in its composition has its own, special chemical properties. However, it can be said that natural gas is characterized by combustion, and of all the substances that make up natural gas in air, only hydrocarbons (methane, ethane, etc.) and carbon monoxide are burned. Natural gas combustion reaction products:

CH 4 + 2O 2 = CO 2 + 2H 2 O;

2C 2 H 6 + 7O 2 = 4CO 2 + 6H 2 O;

2C 3 H 8 + 10O 2 = 6CO 2 + 8H 2 O;

2CO + O 2 = 2CO 2.

Physical properties of natural gas

Natural gas, when it is in the bowels of the Earth, can be in a gaseous state (gas deposits), in the form of a gas "cap" of oil and gas fields, dissolved in oil or in water. Pure natural gas is odorless and colorless. The ignition temperature of natural gas is 650C. Natural gas is 1.8 gas lighter than air.

Natural gas production

Natural gas is extracted from the bowels of the Earth using wells. Gas comes out of the bowels due to the fact that the reservoir is under pressure, many times higher than atmospheric. Thus, the driving force is the pressure difference between the formation and the gathering system.

Natural gas applications

The main use of natural gas is as a fuel for heating residential buildings, heating water and cooking; as fuel for cars, boilers, thermal power plants, etc. Also, natural gas is used in the chemical industry (raw material for the production of various organic substances).

Examples of problem solving

EXAMPLE 1

Exercise natural gas from one of the fields contains 85% methane, 6% ethane, 3% carbon monoxide (II), 4.5% carbon dioxide, 1.5% nitrogen and inert gases by volume. How much air is required to burn 1m 3 of this gas. The volume fraction of oxygen in the air is 21%.
Solution Combustion of natural gas in air occurs due to the oxidizing ability of oxygen, which is part of its composition. Among the gases that make up natural gas, only hydrocarbons and carbon monoxide (II) undergo combustion reactions. Let us write down the reaction equations for the combustion of these gases in oxygen.

2CO + O 2 = 2CO 2 (3).

V (CH 4) = 1000 × 0.85 = 850 l;

V (C 2 H 6) = 1000 × 0.06 = 60 liters;

V (CO) = V gas × φ (CO) / 100%;

V (CO) = 1000 × 0.03 = 30 liters.

According to 1 equation n (CH 4): n (O 2) = 1: 2, therefore, n (O 2) = 2 × n (CH 4) = 2 × 850 / 22.4 = 76 mol. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 1 = 76 × 22.4 = 1702 l.

According to equation 2, n (C 2 H 6): n (O 2) = 2: 7, therefore, n (O 2) = 7/2 × n (C 2 H 6) = 7/2 × 60 / 22.4 = 9.4 mol. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 2 = 9.4 × 22.4 = 210.6 liters.

According to equation 3, n (CO): n (O 2) = 2: 1, therefore, n (O 2) = 1/2 × n (CO) = 1/2 × 30 / 22.4 = 0.7 mol. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 3 = 0.7 × 22.4 = 15.7 liters.

V sum = V (O 2) 1 + V (O 2) 2 + V (O 2) 3 = 1702 + 210.6 + 15.7 = 1928.3 liters.

Because the volume fraction of oxygen in the air is 21%, then the volume of air required for the combustion of natural gas:

V = V (O 2) sum / 0.21 = 1928.3 / 0.21 = 9182 l = 0.9182 m 3.

Answer Air volume - 0.9182 m3.

EXAMPLE 2

Exercise natural gas from one of the fields contains 92% methane, 4% ethane, 7% propane, 2% carbon dioxide and 1% nitrogen. How much oxygen is required to burn 200 liters of this gas.
Solution Among the gases that make up natural gas, only hydrocarbons undergo combustion reactions in oxygen. Let us write down the reaction equations for the combustion of these gases in oxygen.

CH 4 + 2O 2 = CO 2 + 2H 2 O (1);

2C 2 H 6 + 7O 2 = 4CO 2 + 6H 2 O (2);

2C 3 H 8 + 10O 2 = 6CO 2 + 8H 2 O (3).

Let us find the volumes of combustion gases, knowing their volume fractions (see the problem statement):

V (CH 4) = V gas × φ (CH 4) / 100%;

V (CH 4) = 200 x 0.92 = 184 L;

V (C 2 H 6) = V gas × φ (C 2 H 6) / 100%;

V (C 2 H 6) = 200 × 0.04 = 8 l;

V (C 3 H 8) = V gas × φ (C 3 H 8) / 100%;

V (C 3 H 8) = 200 × 0.01 = 2 liters.

According to 1 equation n (CH 4): n (O 2) = 1: 2, therefore, n (O 2) = 2 × n (CH 4) = 2 × 184 / 22.4 = 16 mol. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 1 = 16 × 22.4 = 358.4 liters.

According to equation 2, n (C 2 H 6): n (O 2) = 2: 7, therefore, n (O 2) = 7/2 × n (C 2 H 6) = 7/2 × 8 / 22.4 = 1.25 mol. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 2 = 1.25 × 22.4 = 28 liters.

According to equation 3, n (C 3 H 8): n (O 2) = 2:10, therefore, n (O 2) = 5 × n (C 3 H 8) = 5 × 2 / 22.4 = 0.4 mole. Then the volume of oxygen required for combustion of 850 liters of methane:

V (O 2) 3 = 0.4 × 22.4 = 8.96 liters.

The total volume of oxygen spent on natural gas combustion will be:

V sum = V (O 2) 1 + V (O 2) 2 + V (O 2) 3 = 358.4 + 28 + 8.96 = 395.36 liters.

Answer The oxygen volume is 395.36 liters.

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